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. 2012 Mar 1;68(Pt 3):m306.
doi: 10.1107/S1600536812006022. Epub 2012 Feb 17.

(Acetyl-acetonato-κO,O')bis-[2-(5-methyl-3-phenyl-pyrazin-2-yl-κN)phen-yl-κC]iridium(III)

Guo-Ping Ge  1 , Chun-Yan Li, Cheng-Hao Gu, Mao-He Li, Xiao-Nan Xu
Affiliations

(Acetyl-acetonato-κO,O')bis-[2-(5-methyl-3-phenyl-pyrazin-2-yl-κN)phen-yl-κC]iridium(III)

Guo-Ping Ge et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title complex, [Ir(C(17)H(13)N(2))(2)(C(5)H(7)O(2))], the Ir(III) atom is hexa-coordinated in a distorted octa-hedral geometry by two C,N-bidentate 2-(5-methyl-3-phenyl-pyrazin-2-yl)phenyl (mdpp) ligands and one O,O-bidentate acetyl-acetonate ligand. The dihedral angles between the phenyl rings and the pyrazine ring are 9.56 (14) and 58.99 (14)° for one mdpp ligand and 9.34 (14) and 79.94 (15)° for the other.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title complex, showing displacement ellipsoids at the 30% probability level.
See this image and copyright information in PMC

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