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. 2012 Mar 1;68(Pt 3):m348-9.
doi: 10.1107/S1600536812008185. Epub 2012 Feb 29.

Bis[4-amino-N-(pyrimidin-2-yl)benzene-sulfonamidato](1,10-phenanthroline)nickel(II)

Xiu-Feng Hu  1 , Yue Bing, Xing Li, Zu-Ping Kong
Affiliations

Bis[4-amino-N-(pyrimidin-2-yl)benzene-sulfonamidato](1,10-phenanthroline)nickel(II)

Xiu-Feng Hu et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the mononuclear title compound, [Ni(C(10)H(9)N(4)O(2)S)(2)(C(12)H(8)N(2))], the Ni(II) atom has a distorted octa-hedral coordination geometry comprising four N atoms from two 4-amino-N-(pyrimidin-2-yl)benzene-sulfonamidate ligands and two N atoms from a 1,10-phenanthroline ligand. In the crystal, mol-ecules are connected into a three-dimensional supra-molecular network via N-H⋯O hydrogen bonds and weak C-H⋯O and C-H⋯N contacts.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of (I) showing displacement ellipsoids at the 30% probability level.
Fig. 2.
Fig. 2.
Unit-cell contents for (I) viewed in projection down the a axis.
See this image and copyright information in PMC

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