Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2012 Mar 1;68(Pt 3):o725.
doi: 10.1107/S1600536812005636. Epub 2012 Feb 17.

3-Carbamoyl-2,2-dimethyl-cyclo-pentane-1,1-dicarb-oxy-lic acid

Affiliations

3-Carbamoyl-2,2-dimethyl-cyclo-pentane-1,1-dicarb-oxy-lic acid

Volodymyr Knizhnikov et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, C(10)H(15)NO(5), the five-membered cyclo-pentane ring has an envelope conformation, with four atoms lying in a plane (mean deviation = 0.0213 Å), while the fifth atom deviates from this plane by 0.626 (2) Å. A three-dimensional structure is formed through N-H⋯O and O-H⋯O hydrogen bonds between the amide and carb-oxy-lic acid groups and both carb-oxy-lic acid and amide O-atom acceptors.

PubMed Disclaimer

Figures

Fig. 1.
Fig. 1.
The molecular structure and atom numbering scheme for the title compound, showing 50% probability displacement ellipsoids.
Fig. 2.
Fig. 2.
The synthetic route to the title compound (II).

References

    1. Bruker (2007). APEX2 and SAINT Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Bruker (2008). SADABS Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Carter, K. N. (1958). J. Org. Chem. 23, 1409–1411.
    1. Nieto, M. I., Blanco, J. M., Caamano, O., Fernandez, F. & Gomez, G. (1998). Tetrahedron, 54, 7819–7830.
    1. Noyes, W. A. (1894). J. Am. Chem. Soc. 16, 500–511.