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. 2012 May 14;48(38):4561-3.
doi: 10.1039/c2cc31041d. Epub 2012 Mar 30.

A début for base stabilized monoalkylsilylenes

Ramachandran Azhakar  1 , Rajendra S Ghadwal, Herbert W Roesky, Hilke Wolf, Dietmar Stalke
Affiliations

A début for base stabilized monoalkylsilylenes

Ramachandran Azhakar et al. Chem Commun (Camb). .

Abstract

The first base stabilized monoalkylsilylenes LSitBu (2) and LSi[C(SiMe(3))(3)] (3) (L = PhC(NtBu)(2)) were synthesized by the facile metathesis reactions of LitBu and KC(SiMe(3))(3) with LSiCl (1). The reaction of LSitBu (2) with N(2)O afforded the dimer [LSitBu(μ-O)](2) (4) which contains a four-membered Si(2)O(2) ring.

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