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. 2012 May 4;14(9):2195-7.
doi: 10.1021/ol3006419. Epub 2012 Apr 16.

A non-photochemical approach to the bicyclo[3.2.0]heptane core of bielschowskysin

Jean-Baptiste Farcet  1 , Martin Himmelbauer, Johann Mulzer
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A non-photochemical approach to the bicyclo[3.2.0]heptane core of bielschowskysin

Jean-Baptiste Farcet et al. Org Lett. .

Abstract

An asymmetric synthesis of the tricyclic core (-)-1 of the marine diterpene bielschowskysin is described. In particular, a methodology was developed to introduce the crucial quaternary center at C-12.

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