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. 2012 May 18;14(10):2560-3.
doi: 10.1021/ol300861r. Epub 2012 May 9.

Cytosine derivatives form hemiprotonated dimers in solution and the gas phase

Aaron R Moehlig  1 , Katherine E Djernes, V Mahesh Krishnan, Richard J Hooley
Affiliations

Cytosine derivatives form hemiprotonated dimers in solution and the gas phase

Aaron R Moehlig et al. Org Lett. .

Abstract

Hemiprotonated dimers of cytosine derivatives, implicated in the formation of the i-motif of DNA, have been created in solution and the gas phase. The mechanism of dimerization has been analyzed by mass spectrometry and multidimensional NMR spectroscopy.

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