Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2012 Apr 1;68(Pt 4):m514-5.
doi: 10.1107/S1600536812013128. Epub 2012 Mar 31.

{5,5'-Dimeth-oxy-2,2'-[2,2-dimethyl-propane-1,3-diylbis(nitrilo-methanylyl-idene)]diphenolato}palladium(II)

Siti Kamilah Che Soh, Mustaffa Shamsuddin, Mohd Mustaqim Rosli, Hoong-Kun Fun

{5,5'-Dimeth-oxy-2,2'-[2,2-dimethyl-propane-1,3-diylbis(nitrilo-methanylyl-idene)]diphenolato}palladium(II)

Siti Kamilah Che Soh et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, [Pd(C(21)H(24)N(2)O(4))], the complete mol-ecule is generated by crystallographic mirror symmetry with the Pd and three C atoms lying on the mirror plane. The Pd-O and Pd-N distances are 1.9932 (6) and 2.0029 (7) Å, respectively. The dihedral angle between two benzene rings of the ligand is 79.21 (4)°. In the crystal, C-H⋯O hydrogen bonds link the mol-ecules into layers parallel to the ab plane. These planes are further connected by C-H⋯O inter-actions, forming a three-dimensional network.

PubMed Disclaimer

Figures

Fig. 1.
Fig. 1.
The molecular structure, showing 50% probability displacement ellipsoids. Hydrogen atoms are shown as spheres of arbitrary radius.
Fig. 2.
Fig. 2.
The crystal packing of (I). Dashed lines indicate hydrogen bonds. H atoms not involved in the hydrogen bond interactions have been omitted for clarity.
See this image and copyright information in PMC

References

    1. Bruker (2009). APEX2, SAINT and SADABS Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Cosier, J. & Glazer, A. M. (1986). J. Appl. Cryst. 19, 105–107.
    1. Garoufis, A., Hadjikakou, S. K. & Hadjiliadis, N. (2008). Coord. Chem. Rev. 253, 1384–1397.
    1. Gupta, K. C., Sutar, A. K. & Lin, C. C. (2009). Coord. Chem. Rev. 253, 1926–1946.
    1. He, Y. & Cai, C. (2011). Appl. Organomet. Chem. 25, 799–803.