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. 2012 Apr 1;68(Pt 4):o988.
doi: 10.1107/S160053681200846X. Epub 2012 Mar 7.

4-Meth-oxy-N-(4-nitro-benz-yl)aniline

Kamini Kapoor, Vivek K Gupta, Indresh Kumar, Nisar A Mir, Rajni Kant

4-Meth-oxy-N-(4-nitro-benz-yl)aniline

Kamini Kapoor et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, C(14)H(14)N(2)O(3), the nitro group is nearly coplanar with the benzene ring to which it is bonded [dihedral angle = 1.70 (2)°], and this ring is para-substituted by the amino-methyl-ene group. The dihedral angle between the benzene rings is 57.8 (1)°. The crystal structure is stabilized by N-H⋯O and C-H⋯O hydrogen bonds and weak C-H⋯π inter-actions are also observed.

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Figures

Fig. 1.
Fig. 1.
ORTEP view of the molecule with thermal ellipsoids drawn at the 40% probability level. H atoms are shown as small spheres of arbitrary radii.
Fig. 2.
Fig. 2.
The packing arrangement of molecules viewed down the a axis. The broken lines show the intermolecular N—H···O and C—H···O hydrogen bonds.
See this image and copyright information in PMC

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