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. 2012 May 1;68(Pt 5):m666-7.
doi: 10.1107/S1600536812017175. Epub 2012 Apr 25.

Dicarbon-yl[4-(2,6-dimethyl-phenyl-amino)-pent-3-en-2-onato-κ(2)N,O]rhodium(I)

Gertruida J S Venter  1 , Gideon Steyl, Andreas Roodt
Affiliations

Dicarbon-yl[4-(2,6-dimethyl-phenyl-amino)-pent-3-en-2-onato-κ(2)N,O]rhodium(I)

Gertruida J S Venter et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, [Rh(C(13)H(16)NO)(CO)(2)], a square-planar coordination geometry is observed around the Rh(I) atom, formed by the N and O atoms of the bidentate ligand and two C atoms from two carbonyl ligands. The Rh(I) atom is displaced from the plane through these surrounding atoms by 0.0085 (2) Å. The dihedral angle between the benzene ring and the N-C-C-C-O plane is 89.82 (6)°, and the N-Rh-O bite angle for the bidentate ligand is 90.53 (6)°. An inter-molecular C-H⋯O inter-action is observed between a methyl group of the benzene ring and a carbonyl O atom.

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Figures

Fig. 1.
Fig. 1.
Molecular structure of the title compound. Displacement ellipsoids are drawn at the 50% probability level.
See this image and copyright information in PMC

References

    1. Brandenburg, K. & Putz, H. (1999). DIAMOND Crystal Impact GbR, Bonn, Germany.
    1. Brink, A., Visser, H. G., Steyl, G. & Roodt, A. (2010). Dalton Trans. 39, 5572–5578. - PubMed
    1. Bruker (2001). SADABS Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Bruker (2007). APEX2 and SAINT-Plus Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Cornils, B. & Herrmann, W. A. (1996). In Applied Homogeneous Catalysis with Organometallic Compounds. A Comprehensive Handbook Weinheim: VCH.

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