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. 2012 May 1;68(Pt 5):o1508-9.
doi: 10.1107/S1600536812016194. Epub 2012 Apr 25.

11-(4-Meth-oxy-phen-yl)-3,3-dimethyl-2,3,4,5,10,11-hexa-hydro-1H-dibenzo[b,e][1,4]diazepin-1-one monohydrate

Olatomide A Fadare, Pius O Adelani, Adebomi A Ikotun, Craig A Obafemi

11-(4-Meth-oxy-phen-yl)-3,3-dimethyl-2,3,4,5,10,11-hexa-hydro-1H-dibenzo[b,e][1,4]diazepin-1-one monohydrate

Olatomide A Fadare et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, C(22)H(24)N(2)O(2)·H(2)O, the co-crystallized water mol-ecule inter-acts with the N and O atoms of the mol-ecule through O(w)-H⋯N, O(w)-H⋯O(meth-yl) and N-H⋯O(w) hydrogen-bonding inter-actions. These hydrogen bonds, along with the inter-molecular N-H⋯O=C hydrogen-bonding inter-actions, connect the mol-ecules into a three-dimensional network. The dihedral angle between the two aromatic rings is 65.46 (10)°.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound showing the labelled atoms; thermal ellipsoids are drawn at the 20% probability level.
Fig. 2.
Fig. 2.
The packing diagram (ball and stick model) of the title compound, viewed along c-direction. Hydrogen bonds are drawn as dashed lines.
Fig. 3.
Fig. 3.
Reaction scheme of synthesis of the title compound.
See this image and copyright information in PMC

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