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. 2012 May 1;68(Pt 5):o1550.
doi: 10.1107/S1600536812016030. Epub 2012 Apr 28.

Bis(N-methyl-N-phenyl-carbamo-yl)disulfane

Alayne L Schroll, Maren Pink, George Barany

Bis(N-methyl-N-phenyl-carbamo-yl)disulfane

Alayne L Schroll et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, C(16)H(16)N(2)O(2)S(2), has been synthesized by several different high-yield routes, and has been encountered as a co-product in a number of reaction pathways, ever since it became of inter-est to our research program over 30 years ago. We now confirm the proposed mol-ecular structure in which the mol-ecule exhibits a twofold axis of symmetry through the mid-point of the S-S bond and the two planes defined by the (carbamo-yl)sulfenyl moieties are essentially perpendicular to each other [dihedral angle = 81.55 (14)°].

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Figures

Fig. 1.
Fig. 1.
Crystallographic structure of the title compound showing 50% probability displacement ellipsoids and with all non-hydrogen atoms labelled and numbered.
See this image and copyright information in PMC

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