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. 2012 Apr 1;68(Pt 4):o1221.
doi: 10.1107/S1600536812012597. Epub 2012 Mar 28.

4-Nitro-2-{[(tricyclo-[3.3.1.1(3,7)]decan-1-yl)iminium-yl]meth-yl}phenolate

Kwang Ha  1
Affiliations

4-Nitro-2-{[(tricyclo-[3.3.1.1(3,7)]decan-1-yl)iminium-yl]meth-yl}phenolate

Kwang Ha. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, C(17)H(20)N(2)O(3), is a Schiff base, which is found as a zwitterion in the solid state. The geometry around the iminium N atom indicates sp(2)-hybridization. The zwitterion shows a strong intra-molecular N-H⋯O hydrogen-bond inter-action between the iminium N atom and the phenolate O atom.

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Figures

Fig. 1.
Fig. 1.
Molecular structure of the title compound, with atom numbering. Displacement ellipsoids are drawn at the 40% probability level for non-H atoms.
See this image and copyright information in PMC

References

    1. Bruker (2000). SADABS, SMART and SAINT Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Farrugia, L. J. (1997). J. Appl. Cryst. 30, 565.
    1. Fernández-G, J. M., del Rio-Portilla, F., Quiroz-García, B., Toscano, R. A. & Salcedo, R. (2001). J. Mol. Struct. 561, 197–207.
    1. Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. - PubMed