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. 2012 Jul 9;51(28):7020-3.
doi: 10.1002/anie.201203109. Epub 2012 May 31.

Bis[N,N'-diisopropylbenzamidinato(-)]silicon(II): a silicon(II) compound with both a bidentate and a monodentate amidinato ligand

Konstantin Junold  1 , Johannes A Baus, Christian Burschka, Reinhold Tacke
Affiliations

Bis[N,N'-diisopropylbenzamidinato(-)]silicon(II): a silicon(II) compound with both a bidentate and a monodentate amidinato ligand

Konstantin Junold et al. Angew Chem Int Ed Engl. .

Abstract

Well looked-after: reductive HCl elimination of the λ(6)-silicon(IV) complex 1 leads to the λ(3)-silicon(II) species 2, a novel type of donor-stabilized silylene. Reaction of 2 with [W(CO)(6)] and with I(2) yields the λ(5)-silicon(II) complex 3 and the λ(6)-silicon(IV) complex 4, respectively.

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