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. 2012 Jun 1;68(Pt 6):m823.
doi: 10.1107/S1600536812023069. Epub 2012 May 26.

Hexa-kis-(dimethyl-formamide-κO)manganese(II) (dimethyl-formamide-κO)pentakis(-thio-cyanato--κN)chromate(III)

Valentyna V Semenaka, Oksana V Nesterova, Vladimir N Kokozay, Irina V Omelchenko, Oleg V Shishkin

Hexa-kis-(dimethyl-formamide-κO)manganese(II) (dimethyl-formamide-κO)pentakis(-thio-cyanato--κN)chromate(III)

Valentyna V Semenaka et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, [Mn(C(3)H(7)NO)(6)][Cr(NCS)(5)(C(3)H(7)NO)], was obtained unintentionally as a product of an attempted synthesis of heterometallic complexes based on Reineckes anion using manganese powder, Reineckes salt and 1-(2-hy-droxy-eth-yl)tetra-zole as starting materials. The crystal structure of the complex consists of an [Mn(dmf)(6)](2+) cation and a [Cr(NCS)(5)(dmf)](2-) anion (dmf = dimethyl-formamide). The Mn(II) and Cr(III) atoms show a slightly distorted octa-hedral MnO(6) and CrN(5)O coordination geometries with adjacent angles in the range 85.29 (13)-95.96 (14)°.

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Figures

Fig. 1.
Fig. 1.
Crystal structure of the complex, showing the atom numbering, with 45% probability displacement ellipsoids
See this image and copyright information in PMC

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