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. 2012 Jun 1;68(Pt 6):o1607.
doi: 10.1107/S1600536812019174. Epub 2012 May 5.

4-[(E)-(4-Fluoro-benzyl-idene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione

H C Devarajegowda, S Jeyaseelan, R Sathishkumar, Agnes Sylvia D'souza, Alphonsus D'souza

4-[(E)-(4-Fluoro-benzyl-idene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione

H C Devarajegowda et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the asymmetric unit of the title compound, C(10)H(9)FN(4)S, there are two independent mol-ecules in which the dihedral angles between the 1,2,4-triazole and benzene rings are 36.85 (10) and 7.81 (10)°. In the crystal, N-H⋯S inter-actions link pairs of independent mol-ecules into dimers. There are also π-π inter-actions between the triazole and benzene rings of inversion-related pairs of the more planar mol-ecule [centroid-centroid distance = 3.6430 (13) Å].

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound. Displacement ellipsoids are drawn at the 50% probability level.
Fig. 2.
Fig. 2.
The packing of the molecules showing the formation of hydrogen bonds that link inequivalent molecules into dimers via N3A—H3A···S1B and N3A—H3A···S1B.
See this image and copyright information in PMC

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