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. 2012 Jun 1;68(Pt 6):o1706.
doi: 10.1107/S1600536812020971. Epub 2012 May 12.

N-Methyl-pyrrolidine-1-carbothio-amide

M Naveed Umar, M Nawaz Tahir, Mohammad Shoaib, Akbar Ali, Imran Khan

N-Methyl-pyrrolidine-1-carbothio-amide

M Naveed Umar et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

There are two independent mol-ecules in the asymmetric unit of the title compound, C(6)H(12)N(2)S, in which the N-methyl-thio-formamide unit and the pyrrolidine ring mean plane are oriented at dihedral angles of 5.9 (5) and 5.9 (4)°. In the crystal, zigzag C(4) chains extending along the a axis are formed due to N-H⋯S hydrogen bonds between alternate arrangements of mol-ecules. The chains are inter-linked by C-H⋯S hydrogen bonds.

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Figures

Fig. 1.
Fig. 1.
View of the title compound with the atom numbering scheme. The thermal ellipsoids are drawn at the 50% probability level.
Fig. 2.
Fig. 2.
The partial packing (PLATON; Spek, 2009) which shows that molecules are interlinked to form polymeric chains along the a-axis. The H-atoms not involved in H-bonding are omitted for clarity.
See this image and copyright information in PMC

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