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. 2012 Jun 1;68(Pt 6):o1953.
doi: 10.1107/S160053681202418X. Epub 2012 May 31.

1-Methyl-2-({[(2-methyl-phen-yl)meth-yl]disulfan-yl}meth-yl)benzene

Shahedeh Tayamon, Thahira Begum S A Ravoof, Mohamed Ibrahim Mohamed Tahir, Karen A Crouse, Edward R T Tiekink

1-Methyl-2-({[(2-methyl-phen-yl)meth-yl]disulfan-yl}meth-yl)benzene

Shahedeh Tayamon et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title disulfide, C(16)H(18)S(2), the mol-ecule is twisted about the central S-S bond [the C-S-S-C torsion angle = 93.24 (7)°] and the dihedral angle between the benzene rings is 72.84 (7)°, indicating an almost orthogonal relationship; the methyl groups are orientated to the same side of the mol-ecule. The crystal packing features C-H⋯.π inter-actions which consolidate a three-dimensional architecture.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of (I) showing the atom-labelling scheme and displacement ellipsoids at the 50% probability level.
Fig. 2.
Fig. 2.
A view in projection down the b axis of the unit-cell contents for (I). The C—H···π interactions are shown as purple dashed lines.
See this image and copyright information in PMC

References

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