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. 2012 Sep 7;41(33):9852-4.
doi: 10.1039/c2dt30502j. Epub 2012 Jul 10.

A regioselective Huisgen reaction inside a Keplerate polyoxomolybdate nanoreactor

Claire Besson  1 , Sebastian Schmitz, Kimberly M Capella, Sivil Kopilevich, Ira A Weinstock, Paul Kögerler
Affiliations

A regioselective Huisgen reaction inside a Keplerate polyoxomolybdate nanoreactor

Claire Besson et al. Dalton Trans. .

Abstract

A 1,3-dipolar cycloaddition reaction taking place quantitatively between propiolic acid "guests" and azide functions previously attached to binding sites within the cavity of a {Mo(132)}-type Keplerate reproducibly gives a 2 : 1 ratio of 1,4- and 1,5-triazoles.

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