Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2012 Jul 1;68(Pt 7):o2241.
doi: 10.1107/S1600536812028437. Epub 2012 Jun 30.

2-(3-Meth-oxy-phen-yl)-1,3-dihydro-1,3,2-benzodiaza-borole

Ross S Robinson  1 , Siphamandla Sithebe, Matthew P Akerman
Affiliations

2-(3-Meth-oxy-phen-yl)-1,3-dihydro-1,3,2-benzodiaza-borole

Ross S Robinson et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, C(13)H(13)BN(2)O, is one in a series of 1,3,2-benzodiaza-boroles featuring a 2-meth-oxy-phenyl substitution at the 2-position in the nitro-gen-boron heterocyle. The dihedral angle between the mean planes of the benzodiaza-borole and 2-meth-oxy-phenyl ring systems is 21.5 (1)°. There is an inter-molecular hydrogen bond between one of the NH groups and the meth-oxy O atom. This hydrogen bond leads to an infinite hydrogen-bonded chain colinear with the a axis.

PubMed Disclaimer

Figures

Fig. 1.
Fig. 1.
Displacement ellipsoid plot of (1) at the 50% probability level.
Fig. 2.
Fig. 2.
Hydrogen bonding interactions in (1), shown as dashed lines, viewed down the b-axis.
See this image and copyright information in PMC

References

    1. Akerman, M. P., Robinson, R. S. & Slabber, C. A. (2011). Acta Cryst. E67, o1873. - PMC - PubMed
    1. Blessing, R. H. (1995). Acta Cryst. A51, 33–38. - PubMed
    1. Cason, C. J. (2002). POV-RAY for Windows Persistence of Vision Raytracer Pty. Ltd, Victoria, Australia.
    1. Macrae, C. F., Edgington, P. R., McCabe, P., Pidcock, E., Shields, G. P., Taylor, R., Towler, M. & van de Streek, J. (2006). J. Appl. Cryst. 39, 453–457.
    1. Maruyama, S. & Kawanishi, Y. (2002). J Mater. Chem. 12, 2245-2249.