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. 2012 Jul 1;68(Pt 7):m970.
doi: 10.1107/S1600536812027985. Epub 2012 Jun 23.

Bis(cyanato-κN)tetra-kis-(2,6-dimethyl-pyrazine-κN(4))nickel(II)

Affiliations

Bis(cyanato-κN)tetra-kis-(2,6-dimethyl-pyrazine-κN(4))nickel(II)

Susanne Wöhlert et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

Reaction of nickel(II) chloride with sodium cyanate and 2,6-di-methyl-pyrazine leads to single crystals of the title com-pound, [Ni(NCO)(2)(C(6)H(8)N(2))(4)]. The nickel(II) cation is located about a centre of inversion and is octa-hedrally coordinated by two cyanate anions and four 2,6-dimethyl-pyrazine ligands, forming discrete complexes.

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Figures

Fig. 1.
Fig. 1.
: Crystal structure of the title compound with labeling and displacement ellipsoids drawn at the 50 % probability level. Symmetry code: i = -x + 3/2, -y + 3/2, -z + 1.

References

    1. Boeckmann, J. & Näther, C. (2010). Dalton Trans. 39, 11019–11026. - PubMed
    1. Boeckmann, J., Wriedt, M. & Näther, C. (2010). Eur. J. Inorg. Chem. pp. 1820–1828.
    1. Brandenburg, K. (2011). DIAMOND Crystal Impact GbR, Bonn, Germany.
    1. Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. - PubMed
    1. Stoe & Cie (2008). X-AREA, X-RED32 and X-SHAPE Stoe & Cie, Darmstadt, Germany.