Bis(cyanato-κN)tetra-kis-(2,6-dimethyl-pyrazine-κN(4))nickel(II)
- PMID: 22807789
- PMCID: PMC3393221
- DOI: 10.1107/S1600536812027985
Bis(cyanato-κN)tetra-kis-(2,6-dimethyl-pyrazine-κN(4))nickel(II)
Abstract
Reaction of nickel(II) chloride with sodium cyanate and 2,6-di-methyl-pyrazine leads to single crystals of the title com-pound, [Ni(NCO)(2)(C(6)H(8)N(2))(4)]. The nickel(II) cation is located about a centre of inversion and is octa-hedrally coordinated by two cyanate anions and four 2,6-dimethyl-pyrazine ligands, forming discrete complexes.
Figures
References
-
- Boeckmann, J. & Näther, C. (2010). Dalton Trans. 39, 11019–11026. - PubMed
-
- Boeckmann, J., Wriedt, M. & Näther, C. (2010). Eur. J. Inorg. Chem. pp. 1820–1828.
-
- Brandenburg, K. (2011). DIAMOND Crystal Impact GbR, Bonn, Germany.
-
- Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. - PubMed
-
- Stoe & Cie (2008). X-AREA, X-RED32 and X-SHAPE Stoe & Cie, Darmstadt, Germany.
LinkOut - more resources
Full Text Sources
Miscellaneous