Cooperative bimetallic catalysis in asymmetric transformations
- PMID: 22842925
- DOI: 10.1039/c2cs35129c
Cooperative bimetallic catalysis in asymmetric transformations
Abstract
The efficient synthesis of enantioenriched compounds is becoming increasingly important in modern organic, pharmaceutical, and materials chemistry. Recently, chiral cooperative bimetallic catalysts have emerged as a powerful tool to achieve high efficiency and selectivity in asymmetric transformations. This tutorial review highlights strategies and recent advances in cooperative bimetallic catalysts which have been developed for a variety of asymmetric transformations.
Similar articles
-
Recent advances in cooperative bimetallic asymmetric catalysis: dinuclear Schiff base complexes.Chem Commun (Camb). 2014 Feb 4;50(9):1044-57. doi: 10.1039/c3cc47587e. Chem Commun (Camb). 2014. PMID: 24281133
-
Recent progress in asymmetric bifunctional catalysis using multimetallic systems.Acc Chem Res. 2009 Aug 18;42(8):1117-27. doi: 10.1021/ar9000108. Acc Chem Res. 2009. PMID: 19435320
-
Developing a chiral toolbox for asymmetric catalytic reactions.Enantiomer. 1999;4(6):541-55. Enantiomer. 1999. PMID: 10672459
-
Cooperative bimetallic catalysis in asymmetric allylic substitution.Org Biomol Chem. 2017 Nov 29;15(46):9747-9759. doi: 10.1039/c7ob02476b. Org Biomol Chem. 2017. PMID: 29119155 Review.
-
Recent developments in metal catalyzed asymmetric addition of phosphorus nucleophiles.Chem Soc Rev. 2012 Mar 21;41(6):2095-108. doi: 10.1039/c1cs15247e. Epub 2011 Dec 14. Chem Soc Rev. 2012. PMID: 22170516 Review.
Cited by
-
Iodide-enhanced palladium catalysis via formation of iodide-bridged binuclear palladium complex.Commun Chem. 2020 Mar 31;3(1):41. doi: 10.1038/s42004-020-0287-0. Commun Chem. 2020. PMID: 36703411 Free PMC article.
-
Sustainable and practical formation of carbon-carbon and carbon-heteroatom bonds employing organo-alkali metal reagents.Chem Sci. 2022 Dec 21;14(6):1342-1362. doi: 10.1039/d2sc05475b. eCollection 2023 Feb 8. Chem Sci. 2022. PMID: 36794178 Free PMC article. Review.
-
Metal-to-Metal Distance Modulation by Ligand Design: A Case Study of Structure-Property Correlation in Planar Chiral Cyclophanyl Metal Complexes.Chemistry. 2021 Nov 2;27(61):15020-15026. doi: 10.1002/chem.202102336. Epub 2021 Oct 13. Chemistry. 2021. PMID: 34449116 Free PMC article.
-
Added Complexity!-Mechanistic Aspects of Heterobimetallic Complexes for Application in Homogeneous Catalysis.Molecules. 2023 May 22;28(10):4233. doi: 10.3390/molecules28104233. Molecules. 2023. PMID: 37241974 Free PMC article. Review.
-
Small molecule activation with bimetallic systems: a landscape of cooperative reactivity.Chem Commun (Camb). 2022 Oct 6;58(80):11220-11235. doi: 10.1039/d2cc04296g. Chem Commun (Camb). 2022. PMID: 36128973 Free PMC article. Review.
Publication types
MeSH terms
Substances
LinkOut - more resources
Full Text Sources