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. 2012 Aug 17;14(16):4210-3.
doi: 10.1021/ol3018819. Epub 2012 Aug 2.

Ruthenium-catalyzed oxidative C(sp2)-H bond hydroxylation: site-selective C-O bond formation on benzamides

Vedhagiri S Thirunavukkarasu  1 , Jonathan Hubrich, Lutz Ackermann
Affiliations

Ruthenium-catalyzed oxidative C(sp2)-H bond hydroxylation: site-selective C-O bond formation on benzamides

Vedhagiri S Thirunavukkarasu et al. Org Lett. .

Abstract

Well-defined ruthenium carboxylate complexes enabled unprecedented ruthenium-catalyzed C(sp(2))-H hydroxylations on benzamides with PhI(OAc)(2) as the oxidant at a remarkably low catalyst loading of 1.0 mol %.

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