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. 2012 Aug 17;14(16):4230-3.
doi: 10.1021/ol301912a. Epub 2012 Aug 7.

Transition-metal-free electrophilic amination of arylboroxines

Qing Xiao  1 , Leiming Tian, Renchang Tan, Ying Xia, Di Qiu, Yan Zhang, Jianbo Wang
Affiliations

Transition-metal-free electrophilic amination of arylboroxines

Qing Xiao et al. Org Lett. .

Abstract

A transition-metal-free strategy to construct C(sp(2))-N bonds using arylboroxines and O-benzoyl hydroxylamines as coupling partners has been developed. This transformation provides a useful method to access various aromatic amines.

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