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. 2012 Aug 1;68(Pt 8):m1129.
doi: 10.1107/S1600536812033004. Epub 2012 Jul 28.

cis-Diiodido(N,N,N',N'-tetra-methyl-ethylenediamine-κ(2)N,N')palladium(II)

Antonio Abellán-López, María Teresa Chicote-Olalla, Delia Bautista-Cerezo

cis-Diiodido(N,N,N',N'-tetra-methyl-ethylenediamine-κ(2)N,N')palladium(II)

Antonio Abellán-López et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title complex, cis-[PdI(2)(C(6)H(16)N(2))], the Pd(II) atom lies on a crystallographic twofold rotation axis and is four-coordinated by the two N atoms of a chelating N,N,N',N'-tetra-methyl-ethylenediamine ligand [Pd-N = 2.125 (3) Å] and two I atoms [Pd-I = 2.5833 (4) Å], displaying a distorted square-planar geometry (r.m.s. deviation = 0.005 Å), imposed by the small bite of the chelating ligand [N-Pd-N angle = 84.68 (18)°].

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound. Ellipsoids represent 50% probability levels.
Fig. 2.
Fig. 2.
Packing diagram of the title compound view down b axis Hydrogen atoms are omitted.
See this image and copyright information in PMC

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