Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2012 Aug 1;68(Pt 8):o2507-8.
doi: 10.1107/S1600536812032060. Epub 2012 Jul 21.

(E)-2-{[(2-Amino-pyridin-3-yl)imino]-meth-yl}-4,6-di-tert-butyl-phenol

Alexander Carreño, Sonia Ladeira, Annie Castel, Andres Vega, Ivonne Chavez

(E)-2-{[(2-Amino-pyridin-3-yl)imino]-meth-yl}-4,6-di-tert-butyl-phenol

Alexander Carreño et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, C(20)H(27)N(3)O, the hy-droxy group forms an intra-molecular O-H⋯N hydrogen bond with the imino N atom. The dihedral angle between the aromatic rings is 33.09 (9)°. In the crystal, mol-ecules form centrosymmetric dimers via pairs of N-H⋯N hydrogen bonds involving amino-pyridine fragments.

PubMed Disclaimer

Figures

Fig. 1.
Fig. 1.
Molecular structure of the title compound showing atom labelling scheme and the intramolecular hydrogen bond. Thermal ellipsoids are drawn at the 50% probability level.
Fig. 2.
Fig. 2.
Hydrogen-bonded molecular dimers in the crystal. Symmetry code: (i) -x, 2 - y, -1 - z.
Fig. 3.
Fig. 3.
Synthetic route to the title compound.
See this image and copyright information in PMC

References

    1. Benisvy, L., Bill, E., Blake, A. J., Collison, D., Davies, E. S., Garner, C. D., Guindy, C. I., McInnes, E. J. L., McArdle, G., McMaster, J., Wilson, C. & Wolowska, J. (2004). Dalton Trans. pp. 3647–3653. - PubMed
    1. Benisvy, L., Blake, A. J., Collison, D., Davies, E. S., Garner, C. D., McInnes, E. J. L., McMaster, J., Whittaker, G. & Wilson, C. (2003). Dalton Trans. pp. 1975–1985.
    1. Bruker (2009). APEX2, SAINT and SADABS Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Cimerman, Z., Galesic, N. & Bosner, B. (1992). J. Mol. Struct. 274, 131–144.
    1. Farrugia, L. J. (1997). J. Appl. Cryst. 30, 565.