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. 2012 Aug 1;68(Pt 8):o2581.
doi: 10.1107/S1600536812033302. Epub 2012 Jul 28.

2-(1,2,3,4-Tetra-hydro-naphthalen-1-yl-idene)hydrazinecarbothio-amide

2-(1,2,3,4-Tetra-hydro-naphthalen-1-yl-idene)hydrazinecarbothio-amide

Adriano Bof de Oliveira et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The mol-ecular structure of the title compound, C(11)H(13)N(3)S, is not planar: the maximum deviation from the mean plane of the non-H atoms is 0.521 (2) Å for an aliphatic C atom, which corresponds to an envelope conformation for the non-aromatic ring. The hydrazinecarbothio-amide substituent and the benzene ring have maximum deviations from the mean planes through the non-H atoms of 0.0288 (16) and 0.0124 (27) Å, respectively, and the dihedral angle between the two planes is 8.84 (13)°. In the crystal, mol-ecules are linked into chains along [1[Formula: see text]0] by pairs of N-H⋯S hydrogen bonds between mol-ecules related by centres of symmetry.

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Figures

Fig. 1.
Fig. 1.
Molecular structure of the title compound with labeling and displacement ellipsoids drawn at the 40% probability level.
Fig. 2.
Fig. 2.
Crystal structure of the title compound with view along the crystallographic c axis, showing the N—H···S hydrogen bonding as dashed lines.

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