2-(1,2,3,4-Tetra-hydro-naphthalen-1-yl-idene)hydrazinecarbothio-amide

Abstract

The mol-ecular structure of the title compound, C(11)H(13)N(3)S, is not planar: the maximum deviation from the mean plane of the non-H atoms is 0.521 (2) Å for an aliphatic C atom, which corresponds to an envelope conformation for the non-aromatic ring. The hydrazinecarbothio-amide substituent and the benzene ring have maximum deviations from the mean planes through the non-H atoms of 0.0288 (16) and 0.0124 (27) Å, respectively, and the dihedral angle between the two planes is 8.84 (13)°. In the crystal, mol-ecules are linked into chains along [1[Formula: see text]0] by pairs of N-H⋯S hydrogen bonds between mol-ecules related by centres of symmetry.

Fig. 1.

Molecular structure of the title compound with labeling and displacement ellipsoids drawn at the 40% probability level.

Fig. 2.

Crystal structure of the title compound with view along the crystallographic c axis, showing the N—H···S hydrogen bonding as dashed lines.