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. 1996 Sep;8(2):161-70.
doi: 10.1007/BF00211162.

PLUSH TACSY: Homonuclear planar TACSY with two-band selective shaped pulses applied to C(α),C' transfer and C (β),C (aromatic) correlations

T Carlomagno  1 , M Maurer, M Sattler, M G Schwendinger, S J Glaser, C Griesinger
Affiliations

PLUSH TACSY: Homonuclear planar TACSY with two-band selective shaped pulses applied to C(α),C' transfer and C (β),C (aromatic) correlations

T Carlomagno et al. J Biomol NMR. 1996 Sep.

Abstract

A new homonuclear Hartmann-Hahn-type mixing scheme is introduced that effects coherence transfer between resonances in two separated frequency bands. The mixing scheme relies on the irradiation of two-band selective shaped pulses that are expanded in an MLEV-16 supercycle. Similar to heteronuclear Hartmann-Hahn experiments, a planar effective coupling tensor is created. This novel mixing scheme is applied to C(α),C' transfer and to the transfer between C(β) and aromatic carbon spins.

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References

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