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. 2012 Oct 22;51(43):10712-23.
doi: 10.1002/anie.201203280. Epub 2012 Sep 20.

Catalytic, mild, and selective oxyfunctionalization of linear alkanes: current challenges

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Catalytic, mild, and selective oxyfunctionalization of linear alkanes: current challenges

Mélanie Bordeaux et al. Angew Chem Int Ed Engl. .

Abstract

Selective catalysts for sustainable oxidation of alkanes are highly demanded because of the abundance of these molecules in the environment, the possibility to transform them into higher-value compounds, such as chemicals or synthetic fuels, and the fact that, kinetically speaking, this is a difficult reaction. Numerous chemical and biological catalysts have been developed in the lasts decades for this purpose, rendering the overview over this field of chemistry difficult. After giving a definition of the ideal catalyst for alkane oxyfunctionalization, this review aims to present the catalysts available today that are closest to ideal.

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