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. 2012 Nov;68(Pt 11):m300-2.
doi: 10.1107/S0108270112040826. Epub 2012 Oct 18.

trans-Chloridobis[(Z)-1-imino-1-methoxyethane-κN](triphenylphosphane-κP)platinum(II) chloride monohydrate

Daniela Giardina-Papa  1 , Francesco Paolo Intini, Giovanni Natile, Concetta Pacifico
Affiliations

trans-Chloridobis[(Z)-1-imino-1-methoxyethane-κN](triphenylphosphane-κP)platinum(II) chloride monohydrate

Daniela Giardina-Papa et al. Acta Crystallogr C. 2012 Nov.

Abstract

The title compound, [PtCl(C(3)H(7)NO)(2)(C(18)H(15)P)]Cl·H(2)O or trans-[PtCl{Z-HN=C(Me)OMe}(2)(PPh(3))]Cl·H(2)O, crystallizes from an acetone solution of isomeric trans-[PtCl{E-HN=C(Me)OMe}(2)(PPh(3))]Cl. The two HN=C(Me)OMe ligands show typical π-bond delocalization over the N-C-O group [Cini, Caputo, Intini & Natile (1995). Inorg. Chem. 34, 1130-1137] and have the unprecedented Z-anti configuration. The relative orientation of the imino ether ligands is head-to-tail.

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