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. 2012 Oct 1;68(Pt 10):o2934.
doi: 10.1107/S160053681203869X. Epub 2012 Sep 15.

Diphenyl (methyl-amido)-phosphate

Fahimeh Sabbaghi  1 , Mehrdad Pourayoubi, Marek Nečas, Peter Bartoš
Affiliations

Diphenyl (methyl-amido)-phosphate

Fahimeh Sabbaghi et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The N-H bond in the title compound, C(13)H(14)NO(3)P, is syn-oriented relative to the P=O bond. The N atom deviates somewhat from planarity, the sum of the bond angles being 353.3°. The P atom has a distorted tetra-hedral coordination; its bond angles are in the range 93.96 (5)-116.83 (6)°. In the crystal, mol-ecules form centrosymmetric dimers through P=O⋯H-N hydrogen bonds.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound with ellipsoids shown at the 50% probability level; H atoms are drawn as small spheres of arbitrary radii.
Fig. 2.
Fig. 2.
The hydrogen-bonded inversion dimer (pair of P═O···H—N hydrogen bonds is shown by dotted lines) in the crystal structure. The hydrogen atoms not involved in hydrogen bonding have been omitted for clarity.
See this image and copyright information in PMC

References

    1. Macrae, C. F., Bruno, I. J., Chisholm, J. A., Edgington, P. R., McCabe, P., Pidcock, E., Rodriguez-Monge, L., Taylor, R., van de Streek, J. & Wood, P. A. (2008). J Appl Cryst 41, 466–470.
    1. Oxford Diffraction (2009). CrysAlis CCD and CrysAlis RED Oxford Diffraction Ltd, Yarnton, England.
    1. Pourayoubi, M., Nečas, M. & Negari, M. (2012). Acta Cryst. C68, o51–o56. - PubMed
    1. Sabbaghi, F., Pourayoubi, M., Negari, M. & Nečas, M. (2011). Acta Cryst. E67, o2512. - PMC - PubMed
    1. Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. - PubMed