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. 2012 Dec 7;51(50):12551-4.
doi: 10.1002/anie.201206681. Epub 2012 Nov 9.

Copper-promoted trifluoromethylation of primary and secondary alkylboronic acids

Jun Xu  1 , Bin Xiao, Chuan-Qi Xie, Dong-Fen Luo, Lei Liu, Yao Fu
Affiliations

Copper-promoted trifluoromethylation of primary and secondary alkylboronic acids

Jun Xu et al. Angew Chem Int Ed Engl. .

Abstract

New couple: The Cu-promoted trifluoromethylation of primary and secondary alkylboronic acids with TMSCF(3) extends the scope of transition-metal-catalyzed trifluoromethylation reactions to sp(3)-hybridized carbon centers. It also represents one of the first examples for Cu-catalyzed C-C cross-coupling reactions of alkylboronic acid derivatives.

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