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. 2013 May 14;49(39):4214-6.
doi: 10.1039/c2cc37263k. Epub 2012 Dec 5.

Aerobic oxidative N-dealkylation of tertiary amines in aqueous solution catalyzed by rhodium porphyrins

Zhen Ling  1 , Lin Yun, Lianghui Liu, Bing Wu, Xuefeng Fu
Affiliations

Aerobic oxidative N-dealkylation of tertiary amines in aqueous solution catalyzed by rhodium porphyrins

Zhen Ling et al. Chem Commun (Camb). .

Abstract

Aerobic oxidative N-dealkylation of a variety of aliphatic tertiary amines and anilines catalyzed by rhodium(III) tetra (p-sulfonatophenyl) porphyrin ((TSPP)Rh(III)) is achieved in aqueous solution using dioxygen as the sole oxidant.

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