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. 2012 Nov 1;68(Pt 11):o3070.
doi: 10.1107/S1600536812040974. Epub 2012 Oct 6.

(N→B)-4-Methyl-3-pyrid-yl[N-methyl-imino-diacetate-O,O',N]borane

Marek Dąbrowski  1 , Krzysztof Durka, Janusz Serwatowski
Affiliations

(N→B)-4-Methyl-3-pyrid-yl[N-methyl-imino-diacetate-O,O',N]borane

Marek Dąbrowski et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, C(11)H(13)BN(2)O(4), has a rigid bicyclic structure due to an intra-molecular nitro-gen-boron dative bond. The B atom is in a distorted tetra-hedron environment with a B-N bond length of 1.640 (2) Å, which is in good comparison with the values in analogues compounds. In the crystal, the mol-ecules are linked by weak C-H⋯O and C-H⋯N inter-actions, forming a three-dimensional network.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound with the atom numbering scheme. Displacement ellipsoids for non-H atoms are drawn at the 50% probability level.
Fig. 2.
Fig. 2.
A packing diagram of the title compound, viewed along the a axis.
See this image and copyright information in PMC

References

    1. Agilent (2011). CrysAlis PRO Agilent Technologies, Santa Clara, United States.
    1. Brandenburg, K. (2005). DIAMOND Crystal Impact GbR, Bonn, Germany.
    1. Gillis, E. P. & Burke, M. D. (2008). J. Am. Chem. Soc. 130, 14084–14085. - PMC - PubMed
    1. Knapp, D. M., Gillis, E. P. & Burke, M. D. (2009). J. Am. Chem. Soc. 131, 6961–6963. - PMC - PubMed
    1. Mancilla, T., Höp, H., Bravo, G. & Carrillo, L. (1997). Main Group Met. Chem. 20, 31–36.