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. 2013 Feb 1;15(3):718-20.
doi: 10.1021/ol303520h. Epub 2013 Jan 22.

Ruthenium-catalyzed C-H oxygenation on aryl Weinreb amides

Fanzhi Yang  1 , Lutz Ackermann
Affiliations

Ruthenium-catalyzed C-H oxygenation on aryl Weinreb amides

Fanzhi Yang et al. Org Lett. .

Abstract

Versatile ruthenium catalysts enabled unprecedented C-H bond oxygenations of aryl Weinreb amides with ample scope under exceedingly mild reaction conditions, thereby also giving access to valuable ortho-hydroxylated aldehydes. Mechanistic studies provided strong support for a kinetically relevant C-H bond activation.

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