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. 2013 Mar 11;52(11):3195-8.
doi: 10.1002/anie.201209863. Epub 2013 Jan 31.

Protecting-group-free diastereoselective C-C coupling of 1,3-glycols and allyl acetate through site-selective primary alcohol dehydrogenation

Anne-Marie R Dechert-Schmitt  1 , Daniel C Schmitt, Michael J Krische
Affiliations

Protecting-group-free diastereoselective C-C coupling of 1,3-glycols and allyl acetate through site-selective primary alcohol dehydrogenation

Anne-Marie R Dechert-Schmitt et al. Angew Chem Int Ed Engl. .
No abstract available

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Figures

Figure 1
Figure 1
Cyclometallated iridium catalysts for site-selective allylation.
Scheme 1
Scheme 1
Site selective dehydrogenation enables protecting group-free allylation of diols.
Scheme 2
Scheme 2
Synthesis of the C11-C18 fragment of RK-397.a aAs described for Table 1.
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References

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