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. 2013 Mar 21;49(23):2311-3.
doi: 10.1039/c3cc39189b.

A new class of highly solvatochromic dicyano rhenate(I) diimine complexes--synthesis, photophysics and photocatalysis

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A new class of highly solvatochromic dicyano rhenate(I) diimine complexes--synthesis, photophysics and photocatalysis

Larry Tso-Lun Lo et al. Chem Commun (Camb). .

Abstract

A new class of dicarbonyl dicyano rhenate(I) diimine complexes, cis,trans-[Re(CO)(2)(CN)(2)(N-N)](-), with highly environmentally sensitive MLCT absorption and emission properties was synthesised and characterised. Preliminary experiments revealed that these complexes are active photocatalysts for CO(2) reduction.

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