A new class of highly solvatochromic dicyano rhenate(I) diimine complexes--synthesis, photophysics and photocatalysis
- PMID: 23396368
- DOI: 10.1039/c3cc39189b
A new class of highly solvatochromic dicyano rhenate(I) diimine complexes--synthesis, photophysics and photocatalysis
Abstract
A new class of dicarbonyl dicyano rhenate(I) diimine complexes, cis,trans-[Re(CO)(2)(CN)(2)(N-N)](-), with highly environmentally sensitive MLCT absorption and emission properties was synthesised and characterised. Preliminary experiments revealed that these complexes are active photocatalysts for CO(2) reduction.
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