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. 2013 Feb 1;69(Pt 2):o303.
doi: 10.1107/S1600536813002110. Epub 2013 Jan 31.

Acetonyltriphenyl-phospho-nium nitrate

Tidiane Diop  1 , Libasse Diop, Monika Kučeráková, Michal Dušek
Affiliations

Acetonyltriphenyl-phospho-nium nitrate

Tidiane Diop et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

Crystals of the title salt, C(21)H(20)OP(+)·NO(3) (-), are composed of acetonyltriphenyl-phospho-nium cations and nitrate anions that mainly inter-act through electrostatic forces. The P atom in the cation has a slightly distorted tetra-hedral environment, with C-P-C angles ranging from 104.79 (7) to 112.59 (6)°. The sum of O-N-O angles of the nitrate anion is 359.99°, reflecting its trigonal-planar character. C-H⋯O hydrogen bonds help to consolidate the crystal packing.

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Figures

Fig. 1.
Fig. 1.
The molecular entities of the title compound with displacement ellipsoids drawn at the 50% probability level.
Fig. 2.
Fig. 2.
The crystal packing of the title compound.
See this image and copyright information in PMC

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