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. 2013 Apr 14;49(29):3001-3.
doi: 10.1039/c3cc00013c.

Chiral aryl iodide catalysts for the enantioselective synthesis of para-quinols

Kelly A Volp  1 , Andrew M Harned
Affiliations

Chiral aryl iodide catalysts for the enantioselective synthesis of para-quinols

Kelly A Volp et al. Chem Commun (Camb). .

Abstract

Molecular modelling of an iodine(III) phenoxide was used as a starting point in the design of chiral aryl iodide catalysts for stereoselective oxidative dearomatization reactions. Using this approach, catalysts derived from 8-iodotetralone and tartaric acid were constructed and used to synthesize enantioenriched para-quinols from phenols.

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