Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2012 Dec 1;68(Pt 12):m1439.
doi: 10.1107/S1600536812044078. Epub 2012 Nov 3.

1-[(Z)-1-Ferrocenyl-ethyl-idene]thio-carbonohydrazide

Abdullah M Asiri  1 , Muhammad Nadeem Arshad, Muhammad Ishaq, Khalid A Alamry, Muhammad Shafiq
Affiliations

1-[(Z)-1-Ferrocenyl-ethyl-idene]thio-carbonohydrazide

Abdullah M Asiri et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, [Fe(C5H5)(C8H11N4S)], the cyclo-penta-dienyl (Cp) rings of the ferrocene unit are close to being eclipsed. They are inclined to one another at an angle of 1.95 (2)° and lie 3.309 (2)Å away from each other. The ethyl-idene-thio-carbonohydrazide fragment is planar, with an r.m.s. deviation of 0.0347 (2) Å from the mean plane of its eight non-H atoms, and makes dihedral angles of 21.78 (1) and 19.97 (1)° with respect to the two Cp rings. The mol-ecule adopts a trans geometry about the C=N double bond. In the crystal, N-H⋯(N/S) and C-H⋯S inter-actions stack the mol-ecules in an inverse fashion along the b axis.

PubMed Disclaimer

Figures

Fig. 1.
Fig. 1.
The molecular structure of (I) with 50% displacement ellipsoids.
Fig. 2.
Fig. 2.
Unit cell packing diagram showing intermolecular hydrogen bonds, drawn using dashed lines.
See this image and copyright information in PMC

References

    1. Agilent (2012). CrysAlis PRO Agilent Technologies, Yarnton, Oxfordshire, England.
    1. Barbour, L. J. (2001). J. Supramol. Chem. 1, 189–191.
    1. Farrugia, L. J. (1999). J. Appl. Cryst. 32, 837–838.
    1. Li, X. & Du, L.-Z. (2011). Acta Cryst. E67, m1113. - PMC - PubMed
    1. Macrae, C. F., Bruno, I. J., Chisholm, J. A., Edgington, P. R., McCabe, P., Pidcock, E., Rodriguez-Monge, L., Taylor, R., van de Streek, J. & Wood, P. A. (2008). J. Appl. Cryst. 41, 466–470.