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. 2012 Dec 1;68(Pt 12):m1459.
doi: 10.1107/S1600536812044947. Epub 2012 Nov 7.

Bis{bis-[2-(diisopropyl-phosphan-yl)phen-yl]phosphanido-κ(3) P,P',P''}chloridonickel(II)

Consiglia Tedesco  1 , Marina Lamberti, Mina Mazzeo
Affiliations

Bis{bis-[2-(diisopropyl-phosphan-yl)phen-yl]phosphanido-κ(3) P,P',P''}chloridonickel(II)

Consiglia Tedesco et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, [Ni(C24H36P3)Cl], the Ni(II) atom adopts a distorted square-planar geometry with the two neutral P atoms of the tridentate ligand trans to one another. Bond lengths and angles of the phosphide P atom feature a pyramidal geometry of the donor atom, which forms a single bond with the Ni(II) atom, retaining a stereochemically active lone pair.

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Figures

Fig. 1.
Fig. 1.
A view of (1). Displacement ellipsoids are drawn at the 50% probability level. Hydrogen atoms are omitted for clarity.
See this image and copyright information in PMC

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