Bis(μ-2-carb-oxy-methyl-2-hy-droxy-butane-dioato)bis-[diaqua-manganese(II)]-1,2-bis-(pyridin-4-yl)ethene-water (1/1/2)

Abstract

The asymmetric unit of the title compound, [Mn2(C6H6O7)2(H2O)4]·C12H10N2·2H2O, contains half of the centrosymmetric Mn complex dimer, half of a 1,2-bis-(pyridin-4-yl)ethene mol-ecule, which lies across an inversion center, and one water mol-ecule. Two citrate ligands bridge two Mn(II) ions, and each Mn(II) atom is coordinated by four O atoms from the citrate ligands (one from hy-droxy and three from carboxyl-ate groups) and two water O atoms, forming a distorted octa-hedral environment. In the crystal, O-H⋯O and O-H⋯N hydrogen bonds link the centrosymmetric dimers and lattice water mol-ecules into a three-dimensional structure which is further stabilized by inter-molecular π-π inter-actions [centroid-centroid distance = 3.959 (2) Å]. Weak C-H⋯O hydrogen bonding interactions are also observed.

Fig. 1.

The structure of the title compound showing the atom numbering scheme. Displacement ellipsoids are shown at the 50% probability level. The labelled atoms are related to unlabelled atoms by the symmetry codes: [1 - x, 1 - y, 1 - z] for diaqua-bis-(citrato)di-manganese(II) complex and [2 - x, 2 - y,z] for the 1,2-bis(pyridin-4-yl)ethene molecule.