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. 2012 Dec 1;68(Pt 12):o3256.
doi: 10.1107/S1600536812042390. Epub 2012 Nov 3.

N'-[(E)-2,3-Dihy-droxy-benzyl-idene]-2-meth-oxy-benzohydrazide

Affiliations

N'-[(E)-2,3-Dihy-droxy-benzyl-idene]-2-meth-oxy-benzohydrazide

Muhammad Taha et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, C15H14N2O4 adopts an E conformation about the azomethine double bond. Intra-molecular N-H⋯O and O-H⋯N hydrogen bonds generate S(6) rings and help to establish the molecular conformation. The dihedral angle between the benzene rings is 17.84 (10)°. In the crystal, mol-ecules are linked by O-H⋯O and C-H⋯O hydrogen bonds into a two-dimensional network with a herring-bone pattern arranged parallel to the bc plane.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound showing the atom numbering scheme and N—-H···O and O—H···N intramolecular hydrogen bonds (dotted lines). Displacement ellipsoids are drawn at the 30% probability level. H atoms are presented as small spheres of arbitrary radius.
Fig. 2.
Fig. 2.
A view of the O—-H···O and C—H···O hydrogen bonds (dotted lines) in the crystal structure of the title compound. H atoms non-participating in hydrogen-bonding were omitted for clarity.

References

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