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. 2013 Jan 1;69(Pt 1):m20.
doi: 10.1107/S1600536812049240. Epub 2012 Dec 8.

Dichlorido{N-[(5-methyl-thio-phen-2-yl)methyl-idene]-2-(pyridin-2-yl)ethanamine-κ(2) N,N'}palladium(II)

Mduduzi P Radebe  1 , Martin O Onani, William M Motswainyana
Affiliations

Dichlorido{N-[(5-methyl-thio-phen-2-yl)methyl-idene]-2-(pyridin-2-yl)ethanamine-κ(2) N,N'}palladium(II)

Mduduzi P Radebe et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, [PdCl2(C13H14N2S)], the Pd(II) ion is coordinated by two N atoms of the chelating bidentate ligand and two chloride anions, giving rise to a distorted square-planar geometry. The methyl-substituted thio-phene arm and the pyridine ring are connected to the metal cation through N atoms to form a six-membered chelate ring with a boat conformation, making the complex stable.

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Figures

Fig. 1.
Fig. 1.
Molecular structure of the title complex showing 50% probability displacement ellipsoids for non-H atoms.
See this image and copyright information in PMC

References

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