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. 2013 Jan 1;69(Pt 1):o11.
doi: 10.1107/S1600536812048799. Epub 2012 Dec 5.

2-[1-(2-Hy-droxy-6-meth-oxy-phen-yl)ethyl-idene]-N-methyl-hydrazinecarbothio-amide acetonitrile monosolvate

Brian J Anderson  1 , Alexander M Keeler, Kelly A O'Rourke, Shannon T Krauss, Jerry P Jasinski
Affiliations

2-[1-(2-Hy-droxy-6-meth-oxy-phen-yl)ethyl-idene]-N-methyl-hydrazinecarbothio-amide acetonitrile monosolvate

Brian J Anderson et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, C11H15N3O2S·C2H3N, the dihedral angle between the benzene ring and the mean plane of the hydrazinecarbothio-amide group is 75.1 (2)°. In the crystal, the main mol-ecule is linked to the solvent mol-ecule by a weak N-H⋯N hydrogen bond while O-H⋯S hydrogen bonds link the mol-ecules into columns along [100].

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound with the atom numbering scheme. Displacement ellipsoids are drawn at the 50% probability level. A weak H—H···N intramolecular interaction with the solvent acetonitrile molecule is shown with a dashed line. H atoms are presented as small spheres of arbitrary radius.
Fig. 2.
Fig. 2.
Packing diagram viewed along the c axis. Weak H—H···N intramolecular interactions and O—H···S intermolecular interactions which link the molecules into columns along [1 0 0] are shown by dashed lines.
See this image and copyright information in PMC

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