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. 2013 Jan 1;69(Pt 1):o21.
doi: 10.1107/S1600536812048854. Epub 2012 Dec 5.

(±)-3-Benz-yloxy-1-(4-meth-oxy-benz-yl)piperidine-2-thione

Daniel P Pienaar  1 , Sanaz Khorasani, Charles B de Koning, Joseph P Michael
Affiliations

(±)-3-Benz-yloxy-1-(4-meth-oxy-benz-yl)piperidine-2-thione

Daniel P Pienaar et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title mol-ecule, C20H23NO2S, adopts a twisted conformation in which the two aromatic rings connected to the central piperidine ring are orientated trans to each other. An intra-molecular C-H⋯S contact occurs. In the crystal, C-H⋯π and C-H⋯O inter-actions act to stabilize the structure in three dimensions.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of (I), showing the atomic numbering scheme. Displacement ellipsoids are drawn at the 50% probability level.
Fig. 2.
Fig. 2.
C—H···π and C—H···O interactions in the structure of (I). Only the aromatic ring defined by C16—C21 is involved in C—H···π interactions but these act to bring three molecules together.
See this image and copyright information in PMC

References

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