Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2013 Jan 1;69(Pt 1):o5-6.
doi: 10.1107/S1600536812049100. Epub 2012 Dec 5.

2-(4-Meth-oxy-phen-yl)-1-pentyl-4,5-di-phenyl-1H-imidazole

Jim Simpson  1 , Shaaban K Mohamed, Adel A Marzouk, Avtandil H Talybov, Antar A Abdelhamid
Affiliations

2-(4-Meth-oxy-phen-yl)-1-pentyl-4,5-di-phenyl-1H-imidazole

Jim Simpson et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, C27H28N2O, is a lophine (2,4,5-triphenyl-1H-imidazole) derivative with an n-pentyl chain on the amine N atom and a 4-meth-oxy substituent on the benzene ring. The two phenyl and meth-oxy-benzene rings are inclined to the imidazole ring at angles of 25.32 (7), 76.79 (5) and 35.42 (7)°, respectively, while the meth-oxy substituent lies close to the plane of its benzene ring, with a maximum deviation of 0.126 (3) Å for the meth-oxy C atom. In the crystal, inversion dimers linked by pairs of C-H⋯O hydrogen bonds generate R2(2)(22) loops. These dimers are stacked along the a-axis direction.

PubMed Disclaimer

Figures

Fig. 1.
Fig. 1.
The structure of I with ellipsoids drawn at the 50% probability level.
Fig. 2.
Fig. 2.
Crystal packing of I viewed along b showing centrosymmetric dimer formation. Hydrogen bonds are drawn as dashed lines.
Fig. 3.
Fig. 3.
Crystal packing of I showing stacks formed along a. Hydrogen bonds are drawn as dashed lines.
See this image and copyright information in PMC

References

    1. Allen, F. H., Johnson, O., Shields, G. P., Smith, B. R. & Towler, M. (2004). J. Appl. Cryst. 37, 335–338.
    1. Allen, F. H., Kennard, O., Watson, D. G., Brammer, L., Orpen, A. G. & Taylor, R. (1987). J. Chem. Soc. Perkin Trans. 2, pp. S1–19.
    1. Antolini, M., Bozzoli, A., Ghiron, C., Kennedy, G., Rossi, T. & Ursini, A. (1999). Bioorg. Med. Chem. Lett. 9, 1023–1028. - PubMed
    1. Bernstein, J., Davis, R. E., Shimoni, L. & Chang, N.-L. (1995). Angew. Chem. Int. Ed. Engl. 34, 1555–1573.
    1. Bruker (2011). APEX2, SAINT and SADABS Bruker AXS Inc., Madison, Wisconsin, USA.