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. 2013 Mar 1;69(Pt 3):m143.
doi: 10.1107/S1600536813003462. Epub 2013 Feb 9.

Tris[dimethyl (benzoyl-amido)-phosphato-κ(2) O,O'](1,10-phenanthroline-κ(2) N,N')neodymium(III)

Nataliia S Kariaka  1 , Victor A Trush, Volodymyr V Medviediev, Tetyana Yu Sliva, Vladimir M Amirkhanov
Affiliations

Tris[dimethyl (benzoyl-amido)-phosphato-κ(2) O,O'](1,10-phenanthroline-κ(2) N,N')neodymium(III)

Nataliia S Kariaka et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In both independent mol-ecules of the title compound, [Nd(C9H11NO4P)3(C12H8N2)], the Nd(III) atom is coordinated by six O atoms belonging to three phosphoryl ligands and two N atoms of 1,10-phenanthroline in a dodeca-hedral geometry. In the phosphoryl ligands, the benzene rings are twisted with respect to the planes of the sp(2)-hybridized C atoms of the chelate rings by 12.1 (1)-24.7 (1)°.

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Figures

Fig. 1.
Fig. 1.
View of [NdL3Phen] molecule (Molecule 1) with atom numbering scheme. H atoms have been omitted.
Fig. 2.
Fig. 2.
Polyhedron of Nd1 coordination center.
See this image and copyright information in PMC

References

    1. Agilent (2012). CrysAlis PRO Agilent Technologies, Yarnton, England.
    1. Derkach, G. I., Shokol, V. A. & Kirsanov, A. V. (1960). Zh. Obshch. Khim. 10, 3393–3396.
    1. Kirsanov, A. V. (1954). Dokl. Akad. Nauk SSSR, 4, 646-655.
    1. Legendziewicz, J., Oczko, G., Amirkhanov, V., Wiglusz, R. & Ovchynnikov, V. (2000). J. Alloys Compd, 300–301, 360–369.
    1. Malandrino, G., Fragala, I., Aime, S., Dastru, W., Gobetto, R. & Benelli, C. (1998). J. Chem. Soc. Dalton Trans. pp. 1509–1512.