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. 2013 Mar 1;69(Pt 3):o382.
doi: 10.1107/S1600536813003966. Epub 2013 Feb 16.

2,2-Dibenzyl-hydrazin-1-ium chloride

Shahedeh Tayamon  1 , Thahira Begum S A Ravoof, Mohamed Ibrahim Mohamed Tahir, Karen A Crouse, Edward R T Tiekink
Affiliations

2,2-Dibenzyl-hydrazin-1-ium chloride

Shahedeh Tayamon et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title salt, C14H17N2(+)·Cl(-), the central N atom is pyramidal (sum of bond angles = 330.9°) and there is a near orthogonal relationship between the benzene rings [dihedral angle = 89.95 (10)°]. The crystal packing features N-H⋯Cl hydrogen bonds, which lead to a supra-molecular undulating ribbon along the a axis comprising edge-shared eight-membered {⋯HNH⋯Cl}2 synthons. The chains are connected into layers in the ab plane by C-H⋯π inter-actions.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of salt (I) showing displacement ellipsoids at the 50% probability level.
Fig. 2.
Fig. 2.
A view of the undulating supramolecular chain in (I) mediated by N—H···Cl hydrogen bonds (blue dashed lines) along the a axis.
Fig. 3.
Fig. 3.
A view of the crystal packing in projection down the a axis. The N—H···Cl and C—H···π interactions are shown as blue and purple dashed lines, respectively.
See this image and copyright information in PMC

References

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