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. 2013 Jun 7;42(21):7693-8.
doi: 10.1039/c3dt50273b.

Slow magnetic relaxation in a cyano-bridged ferromagnetic {Fe(III)Ni(II)} alternating chain

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Slow magnetic relaxation in a cyano-bridged ferromagnetic {Fe(III)Ni(II)} alternating chain

Da-Peng Dong et al. Dalton Trans. .

Abstract

A cyano-bridged ferromagnetic {Fe(III)Ni(II)} alternating chain {[Fe(pzTp)(CN)3][Ni(chxn)2]}·ClO4·H2O (1) (pzTp = tetrakis(pyrazolyl)borate, chxn = (1R,2R)-1,2-diaminocyclohexane) was synthesized via rational design. Crystal structure analysis and magnetic studies demonstrated that compound had a one-dimensional zigzagging chain-like structure and slow magnetic relaxation.

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