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. 2013 Apr 19;15(8):1938-41.
doi: 10.1021/ol4005905. Epub 2013 Mar 29.

Alder-ene reactions of arynes

Rajdip Karmakar  1 , Phani Mamidipalli, Sang Young Yun, Daesung Lee
Affiliations

Alder-ene reactions of arynes

Rajdip Karmakar et al. Org Lett. .

Erratum in

  • Org Lett. 2014 Feb 7;16(3):1032

Abstract

Efficient Alder-ene reactions of various arynes generated directly from bis-1,3-diynes are described. The reactivity of ene donors with different tethers was examined under thermal and metal-catalyzed conditions, which indicates that both the formation of aryne intermediates and their ene reactions are less sensitive to the catalyst than to the structural features of the substrates.

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